1673-159X

CN 51-1686/N

二氧化碳加氢制甲醇研究进展

Research Progress on Carbon Dioxide Hydrogenation for Methanol Production

  • 摘要: 随着全球能源需求持续上升以及环境污染问题愈加严重,寻找清洁高效的二氧化碳利用途径已成为研究焦点。甲醇作为一种用途广泛的重要化工原料,同时也是一种有前景的新型清洁能源,通过催化加氢将二氧化碳转化为甲醇,不仅能够减少二氧化碳排放,还能有效实现碳资源的循环利用,对缓解能源短缺和环境问题具有重要意义。研发高活性、高选择性和高稳定性的二氧化碳加氢制甲醇催化剂一直是这一过程的关键技术。文章综述了二氧化碳加氢制甲醇的反应机制及催化剂的研究进展,总结了不同催化剂中活性位、载体和结构对催化性能的影响,指出需要在提高活性金属分散度、调控活性金属与载体的相互作用、活性位点H/C比等方面进一步研究,未来可在引入新型载体、优化制备工艺、低温合成甲醇等方面深入探索。

     

    Abstract: With the continuous growth of global energy demand and serious environmental pollution issues, some research is focused on seeking a clean and efficient approach to carbon dioxide utilization. Being an important and widely used chemical raw material, methanol also acts as a new type of clean energy with promising prospects. The conversion of carbon dioxide into methanol by catalytic hydrogenation can both reduce carbon dioxide emission and effectively implement the recycle & utilization of carbon resources, which is of great significance to alleviate the energy shortage and environmental problems. The article reviews the research progress on the reaction mechanisms and catalysts for hydrogenation of carbon dioxide to produce methanol. It summarizes the impact of active sites, supports, and structures on catalytic performance in different catalysts. It points out that further in-depth research is needed on improving the dispersion of active metals, regulating the interaction between active metals and supports, and the H/C ratio at active sites. Future research can focus on introducing new supports, optimizing preparation processes, and synthesizing methanol at low temperatures.

     

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