1673-159X

CN 51-1686/N

氧化亚铜光阴极稳定性提升策略研究进展

Research Progress on Stability Improvement Strategy of Cuprous Oxide Photocathode

  • 摘要: 氧化亚铜(Cu2O)因其独特的能带结构、优异的光响应性能及经济成本,在光电化学(PEC)产氢领域备受关注,成为关键的光阴极材料,但其氧化还原电位位于能带结构内,易在水溶液中受光诱导发生双向腐蚀,影响其稳定性和性能。为此,研究者们致力于开发多种策略提高Cu2O的稳定性。本文系统综述了利用表面修饰、掺杂、晶面调控等改性手段,精准调控Cu2O表面性质、优化电子结构或引入异质元素,显著提升其抗光腐蚀能力,进而增强稳定性。这些改进不仅巩固了Cu2O基础性能,还直接促进了其产氢性能的优化,显示稳定性与产氢效率正相关。此外,本文还指出建立统一Cu2O光阴极稳定性测试标准至关重要,可确保研究可重复性和可比性,有助于在模拟实际应用场景下测试,并为优化设计、改性策略及未来商业化应用提供可靠数据与参考。

     

    Abstract: Cuprous oxide (Cu2O) has become a key photocathode material in the field of photoelectrochemical (PEC) hydrogen production due to its unique band structure, excellent photoresponse performance and economic cost. However, its REDOX potential is located in the band structure, and it is easy to be photoinduced bidirectional corrosion in aqueous solution, which affects its stability and performance. Therefore, researchers are committed to developing various strategies to enhance the performance of Cu2O stability. This paper systematically reviews the surface modification, doping and other modification methods, to accurately regulate the surface properties of Cu2O, optimize the electronic structure or introduce heterogeneous elements, significantly improve its photocorrosion resistance, and thus enhance stability. These improvements not only consolidate the basic performance of Cu2O, but also directly promote the optimization of its hydrogen production performance, and show that stability is positively correlated with hydrogen production efficiency. In addition, the paper highlights the importance of establishing a unified Cu2O photocathode stability test standard to ensure repeatability and comparability of studies, facilitate testing in simulated real-world application scenarios, and provide reliable data and theoretical guidance for optimal design, modification strategies, and future commercial applications.

     

/

返回文章
返回