Low Permittivity Ba(Al0.98Co0.02)2Si2O8-Ba5Si8O21-Based Microwave Dielectric Ceramics for LTCCs
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Abstract
0.7Ba(Al0.98Co0.02)2Si2O8-0.3Ba5Si8O21(BACS-BS)-based microwave dielectric ceramic was prepared by traditional solid-state reaction method. The effects of Li2O-B2O3(1wt%)(L-B) sintering aids on the microstructure, phase composition and microwave dielectric properties were investigated. Deviation between theoretical and experimental permittivity of 0.7BACS-0.3BS+1wt%(L-B) ceramic was discussed. The results show that adding 1wt%(L-B) sintering aids could decrease the sintering temperature of BACS-BS-based to 950 ℃. However, it apparently degrades the microwave dielectric properties. 0.7Ba(Al0.98Co0.02)2Si2O8−0.3Ba5Si8O21+1wt%(Li2O-B2O3) ceramic could be well-sintered at 950 ℃ and show good microwave dielectric properties: εr=7.56, Q×f=13 976 GHz, τf=−6.32 ppm/℃. The good chemical compatibility between the ceramic and Ag electrodes was exhibited, which made it be a promising candidate for the practical applications of LTCC materials.
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