Effect of Fluoride-containing Electrolyte on the Growth of TiO2 Nanotube Arrays
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Abstract
TiO2 nanotube arrays were fabricated on the Ti substrate in an ethylene glycol solution of NH4F via anodic oxidation method. The morphology of TiO2 nanotube arrays was characterized by scanning electron microscope (SEM). At the same time, the growth mechanism of TiO2 nanotube arrays was analyzed. The results show that the TiO2 nanotube displays a cone-shaped structure with one end closed. H+ and F– ions are key to the formation of TiO2 nanotube arrays . By reusing the fluoride-containing electrolyte, the F– ions can be completely converted into TiF62– ions, so as to reduce the harm to the environment. The fluoride-containing electrolyte can be used for 6 times continuously. The characteristic sizes of TiO2 nanotubes can be effectively controlled with the usage count of electrolyte. The length of TiO2 nanotubes increases first and then decreases, which can be adjusted freely within 20 μm, and the diameter of the nanotubes can reach up to about 110 nm.
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