Phase Structure, Crystal Chemistry and Dielectric Property of Oxygen-site Doped Bi1.5ZnNb1.5O7 Ceramics
-
-
Abstract
By substituting F- for O2-, Bi1.5-xCaxZnNb1.5O7 (0.00≤x≤0.30, abbreviated as C-x), Bi1.5-xCaxZnNb1.5O7-yFy (0.00≤x≤0.20, abbreviated as CF-x) ceramics samples were prepared by conventional solid-state reaction method. The way of defect compensation, doping position substitution position, the influence of F- dopant on phase structure, crystal chemistry and dielectric properties of Ca-doped Bi1.5ZnNb1.5O7 (abbreviated as α-BZN) ceramics samples were investigated. The results revealed that F- incorporation declined the solid solution of Ca2+ in α-BZN, and F- was dissolved into the oxygen site of BO6 octahedral. In the same amount of Ca2+ dopant, with F- incorporation, both the dielectric constant and the dielectric loss decreased, which was consistent to the bond valence sums for A4O′. Compared with Ca2+ doping, the bond valence sums for A4O′ of F- and Ca2+ co-doping increased. The shift of the dielectric constant peak to higher temperature could be associated with the increase in activation energy due to the addition of F-.
-
-